Aldehyde end-capped CO2-based polycarbonates: a green synthetic platform for site-specific functionalization. Issue 12 (7th March 2022)

• Record Type: Journal Article
• Authors: Wang, Molin; Liu, Shunjie; Chen, Xuesi; Wang, Xianhong; Wang, Fosong
• Is Part Of: Polymer chemistry. Volume 13:Issue 12(2022)
• Page Start: 1731
• Page End: 1738
• Publication Date: 2022-03-07
• Subjects: Polymers -- Periodicals; Macromolecules -- Periodicals; Polymerization -- Periodicals; 547.705
• DOI: 10.1039/d2py00129b
• Languages: English
• ISSNs: 1759-9954

Abstract

Abstract : Aldehyde end-capped CO2 -based polycarbonates were prepared to serve as a green platform for the construction of diverse functional polymers. Abstract : Aldehyde end-capped polymers are unique for their quantitative functionalization degree, and are useful in drug delivery, diagnosis and surface modification. However, relevant research studies have mainly focused on polyolefins as main materials, whose non-biodegradable characters may impede their further applications. To address this issue, we developed a strategy to synthesize aldehyde end-capped CO2 -based polycarbonates, namely the copolymerization of propylene epoxide and CO2 in the presence of 4-formylbenzoic acid as the chain transfer agent. Well-defined polycarbonates were obtained with controllable M n in the range of 3.7–19.0 kg mol −1 and Đ of ∼1.1. The high reactivity aldehyde end groups of polymers permit further post-polymerization. As a proof-of-concept, several typical post-polymerization reactions were performed to diversify functionalities, including regulating hydrophilicity, changing thermal properties, and causing aggregation-induced emission and amino acid conjugation, which suggested the potential of aldehyde end-capped polycarbonates as a green platform to prepare functional materials.