Implementing an Air Suction Effect Induction Strategy to Create Super Thermally Insulating and Superelastic SiC Aerogels. Issue 19 (14th April 2022)

• Record Type: Journal Article
• Authors: Yan, Mingyuan; Zhang, Heping; Fu, Yangyang; Pan, Yuelei; Lun, Zhiyi; Zhang, Zhongxin; He, Pan; Cheng, Xudong
• Is Part Of: Small. Volume 18:Issue 19(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-04-14
• Subjects: air suction effect -- elasticity -- high‐temperature resistance -- silicon carbide aerogels -- super thermal insulation; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.202201039
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract: Silicon carbide (SiC) aerogels are promising thermal insulators that are lightweight and possess high thermal stability. However, their application is hindered by their brittleness. Herein, an air suction effect induction (ASEI) strategy is proposed to fabricate a super thermally insulating SiC aerogel (STISA). The ASEI strategy exploits the air suction effect to subtly regulate the directional flow of the SiO gas, which can induce directional growth and assembly of SiC nanowires to form a directional lamellar structure. The sintering time is significantly reduced by >90%. Significant improvements in the compression and elasticity performance of the STISA are achieved upon the formation of a directional lamellar structure through the ASEI strategy. Moreover, the lamellar structure endows the STISA with an ultralow thermal conductivity of 0.019 W m −1 K −1 . The ASEI strategy paves the way for structural design of advanced ceramic aerogels for super thermal insulation. Abstract : Super thermally insulating silicon carbide (SiC) aerogels are prepared by utilizing the air suction effect. The air suction effect skillfully controls mass flow rate of SiO gas. The prepared SiC aerogels with oriented layered structure exhibit excellent mechanical properties and thermal insulation properties. The thermal conductivity of the aerogel is as low as 0.019 W m −1 K −1 .