Wet‐Chemistry: A Useful Tool for Deriving Metal–Organic Frameworks toward Supercapacitors and Secondary Batteries. Issue 13 (25th March 2022)

• Record Type: Journal Article
• Authors: Zhao, Xi; Zheng, Yihe; Dai, Henghan; Yang, Jia; Chen, Qiang; Zhou, Jinyuan; Sun, Gengzhi
• Is Part Of: Advanced materials interfaces. Volume 9:Issue 13(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-03-25
• Subjects: batteries -- metal‐organic frameworks -- supercapacitors -- wet‐chemistry; Materials science -- Periodicals; 620.11
• DOI: 10.1002/admi.202102595
• Languages: English
• ISSNs: 2196-7350

Abstract

Abstract: Metal–organic frameworks (MOFs) possess the advantages of tailorable porosity, adjustable composition, and tunable topologies and are considered promising precursors and self‐templates for the synthesis of complex nanostructures as advanced electrode materials for energy storage. Among various strategies, wet‐chemical method endows better control over topological evolution and compositional transformation of MOF crystals. Herein, the authors comprehensively review the recent achievements on wet‐chemical derivation of MOF via etching, ion‐exchange, hydrolysis, and chemical transformation, underscore the corresponding mechanisms, and highlight their important applications in supercapacitors and secondary batteries. Abstract : Wet‐chemistry method is considered as a promising strategy for controlling the topologies and compositions of active materials toward diverse applications. This article provides a comprehensive review of the wet‐chemical derivation of metal‐organic frameworks, particularly focusing on the underlying mechanisms of etching, ion‐exchange, hydrolysis, and chemical transformation, and highlighting their important applications in supercapacitors and secondary batteries.