A synergistic Cs2CO3 ETL treatment to incorporate Cs cation into perovskite solar cells via two-step scalable fabrication. Issue 12 (16th March 2021)

• Record Type: Journal Article
• Authors: Yavari, Mozhgan; Liu, Xueping; Webb, Thomas; Jayawardena, K. D. G. Imalka; Xiang, Yuren; Kern, Stefanie; Hinder, Steven; Macdonald, Thomas J.; Silva, S. Ravi P.; Sweeney, Stephen J.; Zhang, Wei
• Is Part Of: Journal of materials chemistry. Volume 9:Issue 12(2021)
• Page Start: 4367
• Page End: 4377
• Publication Date: 2021-03-16
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d0tc05877g
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Cs incorporation into perovskite film via a thin Cs2 CO3 layer ETL passivation treatment. Abstract : Triple cation CsFAMA perovskite films fabricated via a one-step method have recently gained attention as an outstanding light-harvesting layer for photovoltaic devices. However, questions remain over the suitability of one-step processes for the production of large-area films, owing to difficulties in controlling the crystallinity, in particular, scaling of the frequently used anti-solvent washing step. This can be mitigated through the use of the two-step method which has recently been used to produce large-area films via techniques such as slot dye coating, spray coating or printing techniques. Nevertheless, the poor solubility of Cs containing salts in IPA solutions has posed a challenge for forming triple cation perovskite films using the two-step method. In this study, we tackle this challenge through fabricating perovskite films on a caesium carbonate (Cs2 CO3 ) precursor layer, enabling Cs incorporation within the film. Synergistically, we find that Cs2 CO3 passivates the SnO2 electron transport layer (ETL) through interactions with Sn 3d orbitals, thereby promoting a reduction in trap states. Devices prepared with Cs2 CO3 treatment also exhibited an improvement in the power conversion efficiency (PCE) from 19.73% in a control device to 20.96% (AM 1.5G, 100 mW cm −2 ) in the champion device. The Cs2 CO3 treated devices (CsFAMA) showed improved stability, with un-encapsulated devices retaining nearly 80% efficiency after 20 days in ambient air.