Aperture control in polymer-based composites with hybrid core–shell spheres for frequency-selective electromagnetic interference shielding. Issue 16 (16th March 2022)

• Record Type: Journal Article
• Authors: Hwang, Uiseok; Kim, Junyoung; Sun, Hanna; Park, In-Kyung; Suhr, Jonghwan; Nam, Jae-Do
• Is Part Of: Journal of materials chemistry. Volume 10:Issue 16(2022)
• Page Start: 8751
• Page End: 8760
• Publication Date: 2022-03-16
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d2ta00045h
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A composite system with embedded bimodal-sized hybrid core–shell spheres is reported for electromagnetic interference (EMI) shielding applications, of which the shells are either wave-diffuse reflecting nickel/gold or wave-absorbing graphene. Abstract : Next-generation electromagnetic interference (EMI) shielding technology requires a frequency-selective capability, which can enable shielding and/or passing electromagnetic (EM) waves of a certain frequency range. Herein, we propose a novel composite system that provides frequency-selective EM wave absorption capability using bimodal-sized hybrid core–shell spheres, which are a combination of two different types of mono-sized core–shell spheres. Both sphere types had polymer cores covered with shells of either wave-diffuse reflecting nickel/gold or wave-absorbing graphene. Notably, the composite exhibited an excellent EMI shielding effectiveness of 96.5 dB at 1 mm due to the synergistic effect of recursive multiple internal diffusive reflections and absorption induced by the spheres. Furthermore, the absorption frequency range and selectivity of EM waves can be controlled in the 8.2–12.4 GHz frequency range by tuning the aperture size, which is specified by the ratio of two types of spheres in the composite. The developed hybrid core–shell spheres and their composites can be tailored with various types of matrices and have enormous potential for special applications, including advanced EMI shielding materials.