Decarbonisation of calcium carbonate at atmospheric temperatures and pressures, with simultaneous CO2 capture, through production of sodium carbonate. Issue 12 (23rd November 2021)

• Record Type: Journal Article
• Authors: Hanein, Theodore; Simoni, Marco; Woo, Chun Long; Provis, John L.; Kinoshita, Hajime
• Is Part Of: Energy & environmental science. Volume 14:Issue 12(2021)
• Page Start: 6595
• Page End: 6604
• Publication Date: 2021-11-23
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/d1ee02637b
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : Novel low-temperature process that, with the availability of green electricity, enables the production of carbon-neutral cement, lime, and soda ash. Abstract : The calcination of calcium carbonate (CaCO3 ) is a major contributor to carbon dioxide (CO2 ) emissions that are changing our climate. Moreover, the calcination process requires high temperatures (∼900 °C). A novel low-temperature process for the decarbonisation of CaCO3 is tested whereby the CO2 is directly sequestered/mineralised in sodium carbonate. CaCO3 is reacted with an aqueous sodium hydroxide solution by mixing under atmospheric temperatures and pressures. The reaction products are calcium hydroxide (hydrated lime; Ca(OH)2 ) and sodium carbonate (soda ash; Na2 CO3 ). For the first time, the extent of this reaction at ambient conditions is studied along with the NaOH requirements. Conceptual process designs, which include procedures to separate and recover material, as well as energy calculations, are also presented to demonstrate the technical/industrial feasibility of the process. The technology is also successfully tested on industrially sourced limestone chalk, and the silica impurity remains inert throughout the process. This technology will enable industrial symbiosis by combining the high-temperature lime and sodium carbonate manufacturing processes into a single low-temperature process and greatly reduce the chemical (raw material) CO2 emissions associated with the production of cement and lime.