Ultra-rapid synthesis of the MgCu2 and Mg2Cu Laves phases and their facile conversion to nanostructured copper with controllable porosity; an energy-efficient, reversible process. Issue 18 (10th September 2021)

• Record Type: Journal Article
• Authors: Fan, Zhen; Baranovas, Gytis; Yu, Holly A.; Szczęsny, Robert; Liu, Wei-Ren; Gregory, Duncan H.
• Is Part Of: Green chemistry. Volume 23:Issue 18(2021)
• Page Start: 6936
• Page End: 6944
• Publication Date: 2021-09-10
• Subjects: Environmental chemistry -- Industrial applications -- Periodicals; Environmental management -- Periodicals; 660
• DOI: 10.1039/d1gc01710a
• Languages: English
• ISSNs: 1463-9262

Abstract

Abstract : Porous copper nanoarchitectures are obtained selectively by acid-dealloying of Mg–Cu precursors prepared by microwave-induced-metal-plasma methods; the entire process is reversible. Abstract : Phase-pure MgCu2 and high-purity Mg2 Cu have been synthesised within 1 min from elemental powders via the microwave-induced metal plasma (MIMP) approach for the first time. Subsequent room temperature, acidic de-alloying led to 3-dimensional nanoporous (NP) Cu within minutes. Each distinctive metallic matrix exhibited a large surface area with a porosity of either 37.47% (from MgCu2 ) or 56.25% (from Mg2 Cu). Both NP Cu powders are composed of crystalline grains ("ligaments") measuring tens of nanometers across, which exhibit rich point- and extended defects. The selection of Laves precursor dictates the form of ligament obtained, which directs the ensuing NP structure. Working electrodes of both types of NP Cu presented reliable linear non-enzymatic sensing properties over glucose concentrations of 0.5–4.5 and 4.5–10.0 mM with high confidence levels (>99%). This study provides a facile, rapid and energy-efficient route to functional NP Cu with eclectic structures, which should be equally applicable to other metals.