A high-performance NiO/TiO2 UV photodetector: the influence of the NiO layer position. Issue 40 (16th September 2021)

• Record Type: Journal Article
• Authors: Yang, Dongmei; Du, Fenqi; Ren, Yuxin; Kang, Tianxin; Hu, Peng; Teng, Feng; Fan, Haibo
• Is Part Of: Journal of materials chemistry. Volume 9:Issue 40(2021)
• Page Start: 14146
• Page End: 14153
• Publication Date: 2021-09-16
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d1tc02687a
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : The influence of NiO layer position in NiO/TiO2 hybrid detectors has been studied. Both devices show highly selective absorption in the ultraviolet range. The D-NT PD showed a low dark current, a high on/off ratio and self-powered performance. Abstract : p–n Junctions have been widely used in the construction of high-performance TiO2 ultraviolet photoelectric detector devices, especially NiO/TiO2 heterostructures. In this work, two devices with different structures were constructed to investigate the effects of the growth of NiO above (S-TN) and below (D-NT) the TiO2 array on the device performance, and the D-NT device showed better performance. The D-NT device exhibited a lower dark current, with a decrease of approximately an order of magnitude compared with S-TN PD and TiO2 nanoarray (NA) PDs. The D-NT heterojunction device demonstrated a large on–off ratio of 5.4 × 10 4, a high detection sensitivity of 1.44 × 10 14 Jones, and a fast photoresponse time of 2 s under UV light illumination. Interestingly, the D-NT device also displayed self-powered performance, and its photoresponse time was 0.1 s. The dense and uniform NiO film deposited on the FTO substrate not only forms a built-in potential field with the TiO2 NAs, but it also provides greater uniformity and stability to this built-in potential field compared to a NiO layer spin-coated on TiO2 NAs, which may be the main reason for the high performance of the D-NT photodetector. The device in which NiO was grown below the TiO2 array provides a fundamental basis for the future development of all-solid-state photodetectors.