Catalytic role of amines in activation of PhICl2 from a computational point of view. Issue 72 (18th August 2021)
- Record Type:
- Journal Article
- Title:
- Catalytic role of amines in activation of PhICl2 from a computational point of view. Issue 72 (18th August 2021)
- Main Title:
- Catalytic role of amines in activation of PhICl2 from a computational point of view
- Authors:
- Farshadfar, Kaveh
Ariafard, Alireza - Abstract:
- Abstract : We thoroughly investigated mechanistic features of dichlorination of diazoacetates using PhICl2 catalysed by pyridine. Abstract : We thoroughly investigated mechanistic features of dichlorination of diazoacetates using PhICl2 catalysed by pyridine. We found that the pyridine serves as a catalyst for decomposition of PhICl2 to PhI and Cl2, leading to the dichlorination step being driven by the in situ generated Cl2 . This type of activation was found to be applicable to other amine-catalysed chlorination reactions using PhICl2 .
- Is Part Of:
- Chemical communications. Volume 57:Issue 72(2021)
- Journal:
- Chemical communications
- Issue:
- Volume 57:Issue 72(2021)
- Issue Display:
- Volume 57, Issue 72 (2021)
- Year:
- 2021
- Volume:
- 57
- Issue:
- 72
- Issue Sort Value:
- 2021-0057-0072-0000
- Page Start:
- 9108
- Page End:
- 9111
- Publication Date:
- 2021-08-18
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d1cc03618a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 21334.xml