A hollow Co9S8 rod–acidified CNT–NiCoLDH composite providing excellent electrochemical performance in asymmetric supercapacitors. Issue 26 (15th June 2021)

• Record Type: Journal Article
• Authors: Sun, Chao; Sun, Li; Fan, Kaifeng; Shi, Yan; Gu, Jialin; Lin, Yifan; Hu, Jingjing; Zhang, Yihe
• Is Part Of: Dalton transactions. Volume 50:Issue 26(2021)
• Page Start: 9283
• Page End: 9292
• Publication Date: 2021-06-15
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt01217g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Co9 S8 hollow rods were wound with aCNTs and then compounded in flower like NiCoLDH to form a unique mosaic structure, providing sharply increased charge transport channels as electrodes for asymmetric supercapacitors. Abstract : Co9 S8 and transition metal hydroxides are both potential pseudo-capacitance electrode materials for supercapacitors. Co9 S8 has a large specific capacitance and electrochemical activity, and transition metal hydroxides have the advantages of high capacitance and redox activity due to their multiple valence metals and open layered structure. In this study, Co9 S8 and NiCoLDH are used to form a Co9 S8 –aCNT–NiCoLDH composite electrode material by twining acidified carbon nanotubes (aCNTs) around hollow Co9 S8 rods and then compounding nickel cobalt hydroxide (NiCoLDH) on the outside. aCNTs provide more electronic channels, which bring more active electrochemical reactions and absorb the volume expansion of Co9 S8 . The hollow Co9 S8 rods and flower-like NiCoLDH structures ensure that the electrode has a highly open structure, which increases the contact area with the electrolyte and is beneficial for ion transport. The outer NiCoLDH can also reduce the volume expansion of Co9 S8 . These advantages ensure the high specific capacitance and rate performance of the Co9 S8 –aCNT–NiCoLDH electrode material. Co9 S8 –aCNT–NiCoLDH was used as the positive material to fabricate asymmetric supercapacitors with attractive energy density and power density, which further proved its excellent electrochemical performance.