ITO-free large area PDLC smart windows: a cost-effective fabrication using spray coated SnO2 on an invisible Al mesh. Issue 40 (7th October 2021)

• Record Type: Journal Article
• Authors: Mondal, Indrajit; S., Kiruthika; Ganesha, Mukhesh K.; Baral, Marlin; Kumar, Ankush; Vimala, S.; Madhuri, P. Lakshmi; Nair, Geetha G.; Prasad, S. Krishna; Singh, Ashutosh K.; Kulkarni, Giridhar U.
• Is Part Of: Journal of materials chemistry. Volume 9:Issue 40(2021)
• Page Start: 23157
• Page End: 23168
• Publication Date: 2021-10-07
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d1ta05820g
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Theoretical and experimental studies are performed to establish the importance of a thin overlayer on metal mesh as an ITO-alternative transparent conducting electrode for liquid crystal smart windows where a uniform electric field is essential. Abstract : Existing liquid crystal (LC) smart window technologies are yet to make inroads into the consumer market largely due to more than 50% of the cost-share of the tin-doped indium oxide (ITO) layer used as the transparent conducting electrode (TCE). In this work, we demonstrate the deployment of a low-cost hybrid TCE as a pathbreaking alternative to ITO in LC smart windows with no compromise in device performance in comparison to standard ITO-based devices. Theoretical modeling puts on a firmer ground the concept of a thin, moderately conducting layer superposed on a micro/nano wire mesh to achieve a uniform electric field, imperative for the efficient operation of LC devices. To illustrate its innovative features, a large-area (10 × 10 cm 2 ) polymer dispersed LC smart window is devised using a hybrid TCE fabricated by spray-coating SnO2 over an Al mesh formed by the self-crack templating method. The device exhibits a high transparency modulation of ∼94% without any degradation even after 400 days. Further, a new idea of a window-cum-display (60 × 50 cm 2 ) with twelve as-fabricated devices assembled in a 4 × 3 matrix having individual and remote control of each row is demonstrated. Bearing commercialization aspects in mind, the entire fabrication is made industry compatible and scalable.