An Inversion Framework for Optimizing Non‐Methane VOC Emissions Using Remote Sensing and Airborne Observations in Northeast Asia During the KORUS‐AQ Field Campaign. Issue 7 (12th April 2022)

• Record Type: Journal Article
• Authors: Choi, Jinkyul; Henze, Daven K.; Cao, Hansen; Nowlan, Caroline R.; González Abad, Gonzalo; Kwon, Hyeong‐Ahn; Lee, Hyung‐Min; Oak, Yujin J.; Park, Rokjin J.; Bates, Kelvin H.; Maasakkers, Joannes D.; Wisthaler, Armin; Weinheimer, Andrew J.
• Is Part Of: Journal of geophysical research. Volume 127:Issue 7(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-04-12
• Subjects: top‐down emissions -- satellite observations -- inverse modeling -- mass balance -- formaldehyde; Atmospheric physics -- Periodicals; Geophysics -- Periodicals; 551.5
• DOI: 10.1029/2021JD035844
• Languages: English
• ISSNs: 2169-897X

Abstract

Abstract: We aim to reduce uncertainties in CH2 O and other volatile organic carbon (VOC) emissions through assimilation of remote sensing data. We first update a three‐dimensional (3D) chemical transport model, GEOS‐Chem with the KORUSv5 anthropogenic emission inventory and inclusion of chemistry for aromatics and C2 H4, leading to modest improvements in simulation of CH2 O (normalized mean bias (NMB): −0.57 to −0.51) and O3 (NMB: −0.25 to −0.19) compared against DC‐8 aircraft measurements during KORUS‐AQ; the mixing ratio of most VOC species are still underestimated. We next constrain VOC emissions using CH2 O observations from two satellites (OMI and OMPS) and the DC‐8 aircraft during KORUS‐AQ. To utilize data from multiple platforms in a consistent manner, we develop a two‐step Hybrid Iterative Finite Difference Mass Balance and four‐dimensional variational inversion system (Hybrid IFDMB‐4DVar). The total VOC emissions throughout the domain increase by 47%. The a posteriori simulation reduces the low biases of simulated CH2 O (NMB: −0.51 to −0.15), O3 (NMB: −0.19 to −0.06), and VOCs. Alterations to the VOC speciation from the 4D‐Var inversion include increases of biogenic isoprene emissions in Korea and anthropogenic emissions in Eastern China. We find that the IFDMB method alone is adequate for reducing the low biases of VOCs in general; however, 4D‐Var provides additional refinement of high‐resolution emissions and their speciation. Defining reasonable emission errors and choosing optimal regularization parameters are crucial parts of the inversion system. Our new hybrid inversion framework can be applied for future air quality campaigns, maximizing the value of integrating measurements from current and upcoming geostationary satellite instruments. Key Points: A two step Hybrid IFDMB‐4DVar inversion system was developed for utilizing data from multiple platforms in a consistent manner VOC DC‐8 emissions in Northeast Asia were constrained using CH2 O concentrations observed by Ozone Monitoring Instrument, Ozone Mapping and Profiler Suite, and DC‐8 aircraft during KORUS‐AQ VOC emissions were increased by 47% leading to improved performance in simulation of O3 and speciated VOCs