Boosting the Ni‐Catalyzed Hydrodeoxygenation (HDO) of Anisole Using Scrap Catalytic Converters. (16th March 2022)

• Record Type: Journal Article
• Authors: Zuliani, Alessio; Kikhtyanin, Oleg; Cova, Camilla Maria; Rodriguez‐Padron, Daily; Kubička, David; Luque, Rafael
• Is Part Of: Advanced sustainable systems. Volume 6:Number 4(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-03-16
• Subjects: anisole -- biofuels -- biomass -- catalytic converters -- hydrodeoxygenation -- lignin -- nickel; Sustainable living -- Periodicals; Sustainability -- Periodicals; Green technology -- Periodicals; Periodicals; 628
• DOI: 10.1002/adsu.202100394
• Languages: English
• ISSNs: 2366-7486

Abstract

Abstract: The large availability and renewable nature of lignin makes its upgrading to bioproducts of particular interest for sustainable development. The hydrodeoxygenation (HDO) of anisole specifically represents a model reaction for the conversion of lignin to biofuels through the removal of the aromatic carbon‐oxygen bonds. To date, a range of Ni‐based catalysts have been reported as highly active systems for the HDO of anisole. However, there has been a substantial lack of consideration given to the environmental characteristics of these catalytic systems, in contrast with the scope of the sustainable production of biofuels. Herein, Ni‐based SiO2 catalysts are prepared by a solventless and highly efficient mechanochemistry approach, having a considerably lower environmental impact as compared to standard impregnation methods. Importantly, scrap catalytic converters (SCATs) are employed as co‐catalysts, proving the possibility of enhancing the catalytic HDO of anisole, with a scarcely exploited waste material. The results demonstrate that the combined use of Ni/SiO2 as catalysts and Ni/SCATs as co‐catalysts remarkably boosts the rate of the conversion of anisole up to more than 50% by achieving an almost complete conversion of anisole in only 40 min instead of at 200 °C and 4 MPa H2 . Abstract : A novel Ni‐based catalytic system for the hydrodeoxygenation of anisole, a lignin model compound, is prepared using a solventless mechanochemical approach. The system is composed of Ni/SiO2, working as a catalyst, and the scrap ceramic cores of catalytic converters, working as a co‐catalyst. The combined system enhances the conversion of anisole over 50% using a cheap, and wideely available waste material.