QEMSCAN® analysis of clay-rich stratigraphy associated with early agricultural contexts at Kuk Swamp, Papua New Guinea. (April 2022)

• Record Type: Journal Article
• Authors: Mason, Joel; Lin, Elaine; Grono, Elle; Denham, Tim
• Is Part Of: Journal of archaeological science. Volume 42(2022)
• Publication Date: 2022-04
• Subjects: Microstratigraphic analysis -- QEM-EDS -- Mineral mapping -- Elemental distributions -- Pedogenesis -- Cultivation practices; Archaeology -- Periodicals; Archaeology -- Research -- Periodicals; 930.1
• DOI: 10.1016/j.jasrep.2022.103356
• Languages: English
• ISSNs: 2352-409X

Abstract

Highlights: QEMSCAN® analysis complements thin section description and X-radiography in the investigation of archaeological stratigraphy. QEMSCAN® analysis enables the investigation of clay-rich stratigraphy, including the discrimination of clay mineral groups: kaolinite, illite, chlorite and smectite. QEMSCAN® mineral maps enable description and interpretation of in situ mineral occurrences and relationships. QEMSCAN® analysis provides elemental maps of key archaeostratigraphic components, indicative of primary and secondary formation processes. QEMSCAN® analysis augments previous interpretations of site formation processes at Kuk Swamp, with a particular focus on early forms of cultivation. Abstract: Quantitative Evaluation of Minerals by Scanning Electron Microscope (QEMSCAN®) provides a diagnostic analytical tool to investigate clay-rich stratigraphy in early agricultural contexts at Kuk Swamp, Papua New Guinea. Previous in situ microstratigraphic analyses at Kuk, comprising thin section description and X-radiography, have been unable to differentiate and characterise clay mineralogy in the archaeological stratigraphy. Although prior X-ray diffraction provided compositional information on clay mineralogy for bulk samples, QEMSCAN® elemental and mineral analyses enable in situ identification and mapping of clay mineral occurrences and relationships. The results of the QEMSCAN® analyses permit reconstruction of the origin and post-depositional transformation of geogenic and biogenic sediments in clay-rich feature fills associated with former plant exploitation and cultivation. QEMSCAN® mineral analyses identify a positive association between smectite-rich contexts and biogenic silica (diatoms and phytoliths) and a negative association between kaolinite-rich contexts and biogenic silica. QEMSCAN® elemental analyses provide valuable information on neoformed minerals, which can be difficult to characterise optically within stratigraphy. These results show the value of QEMSCAN®, especially in combination with thin section micromorphology, to understand the origin and post-depositional formation of clay minerals at archaeological sites in the wet tropics, as well as in other environmental contexts.