Simultaneous determination of actinides and 90Sr in large-size soil and sediment samples. (June 2022)

• Record Type: Journal Article
• Authors: Luo, Maoyi; Liu, Daqian; Yang, Yao; Dai, Xiongxin; Wu, Yang; Shi, keliang
• Is Part Of: Journal of environmental radioactivity. Volume 247(2022)
• Publication Date: 2022-06
• Subjects: Actinides -- 90Sr -- Sequential separation -- TDCR Cherenkov measurement -- ICP-MS -- Large-size soil; TDCR Triple-to-Double Coincidence Ratio -- ICP-MS Inductively Coupled Plasma Mass Spectrometry; Radioactivity -- Periodicals; Radiation, Background -- Periodicals; Radioecology -- Periodicals; Radioactive pollution -- Periodicals; Environmental Pollutants -- Periodicals; Radioactive Pollutants -- Periodicals; Radioactivity -- Periodicals; Radioécologie -- Périodiques; Pollution radioactive -- Périodiques; Fond de rayonnement -- Périodiques; 539.752
• DOI: 10.1016/j.jenvrad.2022.106854
• Languages: English
• ISSNs: 0265-931X

Abstract

Abstract: A simultaneous analytical method for sequential separation and determination of actinides and 90 Sr in large-size environmental samples has been developed. In this method, successive co-precipitation steps were firstly conducted to remove matrix elements, then sequential column separation method was applied for simultaneous separation and purification of actinides and 90 Sr/ 90 Y. By using vacuum box technology, the total analytical time was minimized and batch processing allowed analyzing 12 samples in four days. The activity of 90 Sr was obtained immediately by measuring its daughter radionuclide ( 90 Y) with triple-to-double coincidence ratio (TDCR) Cherenkov counting, while the concentrations of Pu isotopes and 241 Am could be measured by alpha spectrometry and mass spectrometric techniques. The overall recoveries of Pu, Am, Sr and Y were higher than 70% for the entire procedure, while the recovery ratios of Sr/Y were between 0.95 and 1.04 before chromatographic separation. The developed method was verified using 20 g and 50 g of environmental soil samples spiked with certified reference materials IAEA-384 or IAEA-385 and standard solution of 90 Sr/ 90 Y, and good agreement between the expected values and measured results has been achieved. Highlights: Robust method for simultaneous determination of Pu, Am and 90 Sr in large-size soil samples has been developed. XRF was utilized to quickly measure stable Y recovery. The activity of 90 Sr could be obtained by measuring its daughter radionuclide 90 Y with TDCR Cherenkov counting. The method is sufficiently sensitive for detection of global fallout signatures in soil samples.