Effects of different permeable lenses on nitrobenzene transport during air sparging remediation in heterogeneous porous media. (June 2022)

• Record Type: Journal Article
• Authors: Yao, Meng; Bai, Jing; Yang, Xinru; Li, Xiaoyu; Chang, Yuehua; Zhao, Yongsheng
• Is Part Of: Chemosphere. Volume 296(2022)
• Publication Date: 2022-06
• Subjects: Air sparging -- Heterogeneous porous media -- Lens -- Nitrobenzene transport -- Bubbly flow -- Water circulation zone; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2022.134015
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: Air sparging (AS) is considered an effective remediation technology for groundwater contaminated by volatile organic compounds. However, the effects of AS remediation of heterogeneous aquifers with lenses of different permeability are still unclear, which limits the application of AS technology. In this study, the effects of different permeable lenses on nitrobenzene (NB) transport were quantitatively analysed by tracking the temporal and spatial evolutions of the NB concentration and using light transmission visualisation technology to observe airflow. Experimental results showed that the NB outside the airflow zone of the heterogeneous aquifer containing a gravel lens was rapidly removed, which is a special phenomenon. Through moisture content monitoring and colour tracer technology, the bubble-induced water circulation zone in a gravel lens was discovered during AS. At this time, the zone of influence (ZOI) included air flow zone and water circulation zone, while previous studies believed that the ZOI only contained the air flow zone. The presence of water circulation zone in the heterogeneous aquifer with a gravel lens increased the ZOI area and average contaminant removal flux by 5 and 2.3 times, respectively, compared with those in homogeneous aquifer. These findings have modified the conventional cognition about the ZOI and are conducive to an in-depth understanding of the remediation mechanisms and a better design of AS technology in heterogeneous aquifers with different permeable lenses. Graphical abstract: Image 1 Highlights: Bubble-induced water circulation zone during AS was discovered. Airflow migration and nitrobenzene transport were observed by visualisation technology. Emergence cause of water circulation zone was analysed in detail. Water circulation zone clearly increased the ZOI area and contaminant removal flux.