Developing non‐halogen and non‐phosphorous flame retardant bismaleimide resin with high thermal resistance and high toughness through building crosslinked network with Schiff base structure. (31st January 2022)

• Record Type: Journal Article
• Authors: Xu, Wenwen; Yuan, Li; Liang, Guozheng; Gu, Aijuan
• Is Part Of: Polymers for advanced technologies. Volume 33:Number 5(2022)
• Page Start: 1642
• Page End: 1654
• Publication Date: 2022-01-31
• Subjects: bismaleimide resins -- flame retardancy -- halogen‐free and phosphorus‐free -- heat resistance -- Schiff base structure; Polymers -- Periodicals; 668.9
• DOI: 10.1002/pat.5627
• Languages: English
• ISSNs: 1042-7147

Abstract

Abstract: High flame retardancy has become a necessary property for heat‐resistant thermosetting resins (HRTRs) in many cutting‐edge fields. However, developing HRTRs with excellent flame retardancy through sustainable strategy (halogen‐free and phosphorus‐free) is still a great challenge. Herein, a novel halogen‐free and phosphorus‐free allyl compound with Schiff base structure (PDM) was efficiently synthesized from biobased protocatechualdehyde, and then four new flame retarding bismaleimide resins (BP1, BP2, BP3, BP4) were developed by building crosslinked network with PDM. The molar ratio of allyl to imide has a significant effect on performances of BP resins, BP2 resin (its molar ratio of allyl to imide is 0.86) shows the best integrated performances, it has not only high impact strength (14.37 ± 1.1 kJ/m 2 ), but also the highest glass transition temperature (343.5°C) and limiting oxygen index (36.4%) among halogen‐free and phosphorus‐free flame retarding bismaleimide resins reported so far. The investigation on flame retardant mechanism of BP resins shows that the mechanism includes condensed‐phase and gas‐phase flame retarding effects.