Update and critical reanalysis of IUPAC benchmark propagation rate coefficient data. Issue 13 (15th March 2022)

• Record Type: Journal Article
• Authors: Beuermann, Sabine; Harrisson, Simon; Hutchinson, Robin A.; Junkers, Tanja; Russell, Gregory T.
• Is Part Of: Polymer chemistry. Volume 13:Issue 13(2022)
• Page Start: 1891
• Page End: 1900
• Publication Date: 2022-03-15
• Subjects: Polymers -- Periodicals; Macromolecules -- Periodicals; Polymerization -- Periodicals; 547.705
• DOI: 10.1039/d2py00147k
• Languages: English
• ISSNs: 1759-9954

Abstract

Abstract : The dataset used to generate IUPAC benchmark Arrhenius parameters for propagation rate coefficients in radical polymerization is extended and reanalyzed, taking into account systematic interlaboratory variation. Abstract : We present an updated and expanded dataset of benchmark propagation rate coefficient ( k p ) data obtained from pulsed laser polymerization (PLP) of 13 vinyl monomers (styrene, methyl methacrylate, ethyl methacrylate, butyl methacrylate, dodecyl methacrylate, cyclohexyl methacrylate, glycidyl methacrylate, benzyl methacrylate, isobornyl methacrylate, butyl acrylate, methacrylic acid (15% aq. solution), methyl acrylate and vinyl acetate. The data are reanalyzed using a statistical model that takes into account systematic interlaboratory variation, leading to significantly larger joint confidence regions and slightly adjusted figures relative to the original IUPAC benchmark publications. A full set of revised IUPAC benchmark values of pre-exponential factors, activation energies (EA) and k p at 25 °C are presented. 81 independent PLP studies were pooled to give estimates of the standard interlaboratory error in measurements of ln( k p at 25 °C) and E A, which were obtained as 0.08 and 1.4 kJ mol −1, respectively, with a correlation coefficient of 0.04. We recommend that these values be used to estimate the uncertainty in PLP studies that have not been independently replicated.