Synthesis, structure and highly selective C3H8/CH4 and C2H6/CH4 adsorption of a (4, 8)-c ternary flu-metal–organic framework based upon both [Sc4O2(COO)8] and [Cu4OCl6] clusters. Issue 13 (18th March 2022)

• Record Type: Journal Article
• Authors: Ding, Min; Wang, Qian; Cheng, Hongtao; Bai, Junfeng
• Is Part Of: CrystEngComm. Volume 24:Issue 13(2022)
• Page Start: 2388
• Page End: 2392
• Publication Date: 2022-03-18
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/d2ce00133k
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : A new ternary flu -MOF based upon both the torsional cubic 8-c [Sc4 O2 (COO)8 ] cluster and the tetrahedral 4-c [Cu4 OCl6 ] cluster has been successfully synthesized and exhibits highly selective C3 H8 /CH4 and C2 H6 /CH4 adsorption. Abstract : A new ternary flu topological metal–organic framework based upon the torsional cubic 8-connected [Sc4 O2 (COO)8 ] cluster and the tetrahedral 4-connected [Cu4 OCl6 ] cluster, namely, [Sc4 O2 (Cu4 Cl6 O)2 (L)8 ·5H2 O]· x Guest (SNNU-Bai69; SNNU-Bai = Shaanxi Normal University, Bai's group; HL = isonicotinic acid) has been successfully obtained by a solvothermal reaction of ScCl3 ·6H2 O, Cu(NO3 )2 ·3H2 O and HL. Very interestingly, this is the first ternary MOF based upon both the torsional cubic 8-connected [Sc4 O2 (COO)8 ] cluster and the tetrahedral 4-connected [Cu4 OCl6 ] cluster. Furthermore, its gas adsorption isotherms and breakthrough experiments reveal that it exhibits highly selective C3 H8 /CH4, C3 H8 /C2 H6 and C2 H6 /CH4 adsorption and may be used for the pipeline natural gas upgrading.