Binuclear copper iodine cluster-based coordination sheets as photocatalysts for decarboxylative cyanation. Issue 24 (4th March 2022) - Zhong, Bingwen
Abstract : Porous coordination polymers were used as photocatalysts, combining photocatalysis and copper catalysis to realize decarboxylative radical cyanation reactions. Abstract : We synthesized two new MOFs (Cu-Tpxa-1 and Cu-Tpxa-2) that were used as heterogeneous photocatalysts, combining photocatalysis and copper catalysis to achieve decarboxylative radical cyanation reactions. This new heterogeneous catalysis method optimized the redox properties and excited-state lifetimes, providing a new idea for exploring photocatalytic mechanisms.