A new type of phosphate-based phosphor Na3CsMg7(PO4)6:Eu2+/Mn2+ with high quantum efficiency and high thermostability. Issue 9 (15th February 2022)

• Record Type: Journal Article
• Authors: Shi, Lin-Ying; Zhao, Dan; Zhang, Rui-Juan; Zhu, Shuang-Yin; Yu, Meng-Han
• Is Part Of: Dalton transactions. Volume 51:Issue 9(2022)
• Page Start: 3686
• Page End: 3694
• Publication Date: 2022-02-15
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt04393e
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A new type of blue phosphor NCMP: x Eu 2+ was developed with high quantum efficiency and high thermostability. Abstract : The Eu 2+ ion, with the 4f 7 5d 1 electronic configuration, is one of the most important activated ions due to its symmetry-allowed 4f → 5d electron transition. Herein, we successfully prepared a new type of blue phosphor, Na3 CsMg7 (PO4 )6 : x Eu 2+ (NCMP: x Eu 2+ ), in which Eu 2+ occupies the Na + sites of the host lattice. Under 395 nm light excitation, a broad emission band from 410 to 550 nm can be seen, peaking at 458 nm, due to the 5d → 4f transition of Eu 2+ . Moreover, Eu 2+ can be used as a sensitizer ion in an NCMP host. For co-doping phosphor NCMP:0.18Eu 2+ /0.4Mn 2+, both Eu 2+ and Mn 2+ emission bands can be seen using 395 nm as the excitation wavelength for the occurrence of Eu 2+ → Mn 2+ charge transfer. The optimized concentration of Eu 2+ for NCMP: x Eu 2+ is x = 0.18, with high internal (IQE) and external quantum efficiencies (EQE) of 66.4% and 22.8%. The luminescence of NCMP:0.18Eu 2+ has high thermostability with 77.3% the intensity at 450 K compared to that at 300 K. Finally, a white illuminating lamp was produced using a 395 nm UV chip, blue phosphor NCMP: x Eu 2+, green phosphor (Sr, Ba)2 SiO4 :Eu 2+ and red phosphor CaAlSiN3 :Eu 2+ with CIE coordinates of (0.378, 0.369), color temperature (CCT) of 3971 K, and color rendering index ( R a ) of 79.8.