Structure and Low‐temperature Performance of Waste Graphite Used in Lithium‐ion Battery Anode. Issue 8 (22nd February 2022)

• Record Type: Journal Article
• Authors: Dong, Wei; Wang, Wenbo; Shen, Ding; Sun, Wen; Zhao, Mingyuan; Meng, Lingqiang; Yang, Shaobin; Zhu, Xuanyi; Chi, Hailong; Dong, Liang
• Is Part Of: ChemistrySelect. Volume 7:Issue 8(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-02-22
• Subjects: Graphite -- Purification -- Lithium-ion battery -- Low temperature performance; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.202104547
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: Graphite is a very important mineral resource and strategic resource. With the continuous decrease of graphite resources consumption, the recycling of graphite is getting more and more attention. In this work, lithium‐ion battery anode materials were prepared from discarded high‐purity graphite crucibles by crushing, shaping, purification and coating processes, and structural and electrochemical properties of materials were investigated, as well as the low‐temperature charging and discharging performance.The results show that, the initial discharge capacity of TCH sample is 419.4 mAh/g, and the initial coulombic efficiency is 80.4 %. The initial coulombic efficiency reached 88.1 % and the capacity is 345.9 mAh/g after 100 cycles, when the coating amount was 10 wt%. The initial coulombic efficiency, polarization and low temperature properties of carbon coating materials are obviously improved.First‐principles calculations reveal that the reason for the improvement of electrochemical performanceduetothe coating reduces the Li‐ion diffusion barrier. Abstract : The initial coulombic efficiency and low temperature properties of carbon coated materials were significantly improved. The effect of carbon coating on properties of spheroidized graphite were examined by First principles calculations based on the density functional theory (DFT), whichreveals the reason for the improvement of electrochemical performance is the carbon coating reduces the Li ion diffusion barrier.