Solid-state NMR insights into alcohol adsorption by metal–organic frameworks: adsorption state, selectivity, and adsorption-induced phase transitions. Issue 28 (18th March 2022)

• Record Type: Journal Article
• Authors: Khan, Arafat Hossain; Salout, Sara Amanzadeh; Shupletsov, Leonid; De, Ankita; Senkovska, Irena; Kaskel, Stefan; Brunner, Eike
• Is Part Of: Chemical communications. Volume 58:Issue 28(2022)
• Page Start: 4492
• Page End: 4495
• Publication Date: 2022-03-18
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc00638c
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Alcohol adsorption by metal–organic frameworks (ZIF-8 and ZIF-11) in aqueous solutions is investigated including alcohol mixtures. Abstract : Alcohol adsorption by metal–organic frameworks (ZIF-8 and ZIF-11) in aqueous solutions is investigated including alcohol mixtures. Solid-state 13 C NMR spectroscopy is demonstrated to be well-suited for such liquid-phase adsorption studies at the molecular level. Adsorption-induced immobilization could be visualized. Finally, an unexpected phase transition of ZIF-11 was discovered.