Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes. Issue 27 (16th March 2022)
- Record Type:
- Journal Article
- Title:
- Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes. Issue 27 (16th March 2022)
- Main Title:
- Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes
- Authors:
- Shephard, Angus C. G.
Daniels, Daisy P.
Deacon, Glen B.
Guo, Zhifang
Jaroschik, Florian
Junk, Peter C. - Abstract:
- Abstract : Tetra- and penta-phenyl cyclopentadienyldiphenylphosphine pro-ligands have been synthesised, which undergo selective C–P bond cleavage with lanthanoid metals (Ln = Eu, Sm and Yb), providing a new route to divalent octa- and deca-phenylmetallocenes. Abstract : The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C–P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.
- Is Part Of:
- Chemical communications. Volume 58:Issue 27(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 27(2022)
- Issue Display:
- Volume 58, Issue 27 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 27
- Issue Sort Value:
- 2022-0058-0027-0000
- Page Start:
- 4344
- Page End:
- 4347
- Publication Date:
- 2022-03-16
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc00698g ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 21145.xml