Chiral rhodium(iii)–azobenzene complexes as photoswitchable DNA molecular locks. Issue 27 (11th March 2022)
- Record Type:
- Journal Article
- Title:
- Chiral rhodium(iii)–azobenzene complexes as photoswitchable DNA molecular locks. Issue 27 (11th March 2022)
- Main Title:
- Chiral rhodium(iii)–azobenzene complexes as photoswitchable DNA molecular locks
- Authors:
- Lin, Mingwei
Zou, Shanshan
Li, Tingzhen
Karges, Johannes
Chen, Yu
Zhao, Yukun
Ji, Liangnian
Chao, Hui - Abstract:
- Abstract : Two chiral rhodium(iii ) complexes with an azobenzene moiety were developed to act as photoswitchable DNA molecular locks, which can photo-regulate DNA transcription in vitro . Abstract : Chiral rhodium(iii )–azobenzene complexes that are able to intercalate into DNA were developed. Upon light exposure, the azobenzene moiety of the metal complexes can photoisomerize from the trans -form to the cis -form, and strongly stabilize the DNA double-helix and modulate DNA transcription. This study presents the first example of metal-based photoswitchable DNA molecular locks.
- Is Part Of:
- Chemical communications. Volume 58:Issue 27(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 27(2022)
- Issue Display:
- Volume 58, Issue 27 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 27
- Issue Sort Value:
- 2022-0058-0027-0000
- Page Start:
- 4324
- Page End:
- 4327
- Publication Date:
- 2022-03-11
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc00932c ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 21145.xml