Copper(ii)-photocatalyzed decarboxylative oxygenation of carboxylic acids. Issue 28 (24th February 2022)

• Record Type: Journal Article
• Authors: Reichle, Alexander; Sterzel, Hannes; Kreitmeier, Peter; Fayad, Remi; Castellano, Felix N.; Rehbein, Julia; Reiser, Oliver
• Is Part Of: Chemical communications. Volume 58:Issue 28(2022)
• Page Start: 4456
• Page End: 4459
• Publication Date: 2022-02-24
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc00570k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Choosing the right coordination geometry for the light-induced Cu(ii )-catalyzed oxidative decarboxylation. Abstract : Showcasing the concept of light-induced homolysis for the generation of radicals, the Cu II -photocatalyzed decarboxylative oxygenation of carboxylic acids with molecular oxygen as the terminal oxidant is described. Two Cu II -carboxylate complexes with different coordination geometries were synthesized and characterized by X-ray analysis, correlating their structure with their ability to initiate light-induced decarboxylations.