Plant extract-based green fabrication of nickel ferrite (NiFe2O4) nanoparticles: An operative platform for non-enzymatic determination of pentachlorophenol. (May 2022)

• Record Type: Journal Article
• Authors: Taqvi, Syed Iqleem H.; Solangi, Amber R.; Buledi, Jamil A.; Khand, Nadir H.; Junejo, Bindia; Memon, Almas F.; Ameen, Sidra; Bhatti, Atiya; Show, Pau-Loke; Vasseghian, Yasser; Karimi-Maleh, Hassan
• Is Part Of: Chemosphere. Volume 294(2022)
• Publication Date: 2022-05
• Subjects: Nickel ferrite nanoparticles -- Pentachlorophenol -- Pesticides -- Electrochemical sensor -- NiFe2O4/GCE; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2022.133760
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: Environmental pollution has become a major human concern with the extensive exploitation of pesticides. Pentachlorophenol (PCP) is the most hazardous of all chlorophenols which are being used as pesticide, fungicide, and wood preservative. Thus, the fabrication of ultrasensitive electrochemical methods for the determination of pesticides is of great significance. In the present experiment, a simple, green, and sensitive electrochemical sensor was constructed for the determination of PCP by using a chemically modified nickel ferrite glassy carbon electrode (NiFe2 O4 /GCE). The fabricated nanoparticles were primarily characterized by several analytical tools to confirm the functionalities, surface texture, crystallinity, and elemental composition. For the investigation of conductive nature, the proposed NiFe2 O4 /GCE was exploited to the primary electrochemical characterization tools e.g. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The ultra-sensitive determination of PCP was carried out under the linear dynamic range from 0.01 to 90 μM at the pulse amplitude of 80 mV/s in BRB buffer pH of 4. The limit of detection of the developed methods for PCP was calculated to be 0.0016 μM. The analytical applicability of the fabricated sensor was tested in different water samples depicting the acceptable recovery values. Graphical abstract: Green, and sensitive electrochemical sensor based on NiFe2 O4 /GCE for the determination of pentachlorophenol. Image 1 Highlights: A green and sensitive electrochemical sensor was constructed for PCP determination. NiFe2O4 was modified on GCE to generate an electrode NiFe2O4/GCE. Two techniques of CV and EIS were used to detect PCP. The NiFe2O4/GCE was illustrated reproducibility, repeatability, and long-term stability.