Foldable high‐strength electrode enabled by nanosheet subunits for advanced sodium‐ion batteries. Issue 2 (24th August 2021)

• Record Type: Journal Article
• Authors: Wang, Hanwei; Fu, Jinzhou; Wang, Chao; Zhang, Ruiwang; Li, Yingying; Yang, Yushan; Li, Haobo; Sun, Qingfeng; Li, Huiqiao
• Is Part Of: InfoMat. Volume 4:Issue 2(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-08-24
• Subjects: cellulose -- film electrode -- sodium‐ion batteries -- titanium dioxide; Materials -- Periodicals; Information technology -- Periodicals; Smart materials -- Periodicals; 620.11
• DOI: 10.1002/inf2.12241
• Languages: English
• ISSNs: 2567-3165

Abstract

Abstract: Power sources with strong mechanical properties and high‐energy density are highly desirable for the next‐generation flexible electronics. However, the challenge arises from the current electrode structure design, which is unable to bring both satisfactory mechanical and electrochemical properties with high active materials content and mass. Herein, we reported novel flexible, high‐strength, and mechanically stable TiO2 ‐based film electrodes for advanced sodium‐ion batteries, achieving an ultrahigh strength (up to ≈60 MPa) and commercial‐level areal capacity (4.5 mAh cm −2 ). Highly‐dispersed TiO2 and interlaced carbon nanotube (CNT) networks are embedded in the sheet‐liked cellulose to form porous, high‐conductive, and high‐active TiO2 ‐C nanosheets that is basic building subunits of TiO2 ‐C films, allowing the films with structural robustness and origami‐level flexibility. This strategy reconciles the contradiction between mechanical properties and active material content in flexible electrodes, and the fabricated electrode with a high TiO2 content of >65% can be bent more than 11 000 times without breaking. Meanwhile, good capacity and excellent cycle stability (0.02‰ capacity‐decay rate over 9000 cycles) of TiO2 ‐C film under a higher active content (75%) has well satisfied the demands of flexible energy storage devices for electrochemical performances. This TiO2 ‐C subunit assembly methodology demonstrates enormous potential in high‐strength/toughness flexible electrode construction for flexible electronics. Abstract : To address the challenge of balancing high energy density and strong mechanical properties in next‐generation flexible power devices, we developed a novel electrode structure design to construct foldable, high‐strength and high‐performance electrodes by using interlaced CNTs plane embedded highly‐dispersed TiO2 nanoparticles in sheet‐like cellulose as basic building subunits. The fabricated flexible electrodes with hierarchical structure can be folded into paper crane and over ten‐thousand times without fracture in mechanical properties, and can achieve ultralong cycling stability (over nine‐thousand cycles) and a commercial‐level areal capacity in electrochemical properties.