BBr3‐Mediated P(III)‐Directed C−H Borylation of Phosphines. Issue 9 (27th December 2021)
- Record Type:
- Journal Article
- Title:
- BBr3‐Mediated P(III)‐Directed C−H Borylation of Phosphines. Issue 9 (27th December 2021)
- Main Title:
- BBr3‐Mediated P(III)‐Directed C−H Borylation of Phosphines
- Authors:
- Lv, Jiahang
Zhang, Xue‐Jun
Wang, Minyan
Zhao, Yue
Shi, Zhuangzhi - Abstract:
- Abstract: Transition‐metal‐catalyzed C−H borylation has been widely used in the preparation of organoboron compounds. Here, we developed a general protocol on metal‐free P(III)‐directed C−H borylation of phosphines mediated by BBr3, resulting in the formation of products bearing both phosphorus and boron. The development of the metal‐free strategy to mimic previous metallic processes has shown low cost, superior practicality, and environmental friendliness. Density functional theory (DFT) calculations demonstrate the preferred pathway for this metal‐free directed C−H borylation process. Abstract : Boron Chemistry . An efficient metal‐free system has been uncovered for the site‐selective C−H borylation of phosphines directed by P(III) atom just using BBr3 . This robust method enables the rapid construction of phosphine boronate esters in selective, practical, low‐cost, and environmentally friendly modes.
- Is Part Of:
- Chemistry. Volume 28:Issue 9(2022)
- Journal:
- Chemistry
- Issue:
- Volume 28:Issue 9(2022)
- Issue Display:
- Volume 28, Issue 9 (2022)
- Year:
- 2022
- Volume:
- 28
- Issue:
- 9
- Issue Sort Value:
- 2022-0028-0009-0000
- Page Start:
- n/a
- Page End:
- n/a
- Publication Date:
- 2021-12-27
- Subjects:
- C−H borylation -- DFT calculation -- metal-free -- phosphines -- site-selectivity
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3765 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chem.202104100 ↗
- Languages:
- English
- ISSNs:
- 0947-6539
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3168.860500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 21118.xml