Fabrication of Stretchable Superamphiphobic Surfaces with Deformation‐Induced Rearrangeable Structures. Issue 10 (31st January 2022)

• Record Type: Journal Article
• Authors: Zhou, Xiaoteng; Liu, Jie; Liu, Wendong; Steffen, Werner; Butt, Hans‐Jürgen
• Is Part Of: Advanced materials. Volume 34:Issue 10(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-01-31
• Subjects: deformation resistance -- liquid manipulation -- stretchable surfaces -- superamphiphobicity -- wetting; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.202107901
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: Stretchable superamphiphobic surfaces with a high deformation resistance are in demand to achieve liquid‐repellent performance in flexible electronics, artificial skin, and textile dressings. However, it is challenging to make mechanically robust superamphiphobic coatings, which maintain their superliquid repellency in a highly stretched state. Here, a stretchable superamphiphobic surface is reported, on which the microstructures can rearrange during stretching to maintain a stable superamphiphobicity even under a high tensile strain. The surface is prepared by spray‐coating silicone nanofilaments onto a prestretched substrate (e.g., cis ‐1, 4‐polyisoprene) with poly(dimethylsiloxane) (PDMS) layer as a binder. After subsequent fluorination, this surface keeps its superamphiphobicity to both water and n‐hexadecane up to the tensile strain of at least 225%. The binding PDMS layer and rearrangeable structures maximize the deformation resistance of the surface during the stretching process. The superamphiphobicity and morphology of the surface are maintained even after 1000 stretch–release cycles. Taking advantage of the mentioned benefits, a liquid manipulation system is designed, which has the potential for fabricating reusable and low‐cost platforms for biochemical detection and lab‐on‐a‐chip systems. Abstract : A stretchable and durable superamphiphobic surface is fabricated by a simple and low‐cost spray‐coating method. Low‐surface‐tension liquids can easily slide off the surface, even when the tensile strain of the surface is ≥225%.