Geochemical characterization of crude oils and potential source rocks from southern coastal Ecuador: Hypothetical petroleum systems. (April 2022)

• Record Type: Journal Article
• Authors: Márquez, G.; Morato, A.; Guzmán, M.A.; Boente, C.; Witt, C.
• Is Part Of: Marine and petroleum geology. Volume 138(2022)
• Publication Date: 2022-04
• Subjects: Mixed oil -- Biodegradation -- Oil-source rock correlation -- QEDA results -- Progreso Basin province -- Ecuador; Submarine geology -- Periodicals; Petroleum -- Geology -- Periodicals; Géologie sous-marine -- Périodiques; Pétrole -- Géologie -- Périodiques; Petroleum -- Geology; Submarine geology; Periodicals; Electronic journals; 551.468
• DOI: 10.1016/j.marpetgeo.2022.105545
• Languages: English
• ISSNs: 0264-8172

Abstract

Abstract: This research paper encompasses an organic geochemical investigation on oils and sedimentary rocks from the southern coastal region of Ecuador that examines the hydrocarbon generation and accumulation in the strata of Progreso Basin Province. This petroliferous province represents an interesting area for an oil geochemistry study due to its non-elucidated petroleum systems. The present work focuses on the analysis of eighty-five oils and forty rock samples to determine kerogen types, depositional paleoenvironments, levels of thermal maturity, and in-reservoir petroleum biodegradation stages as well as to assess correlations between source facies and oil samples. Potential source rocks were selected and analysed from different outcrops and wells throughout the basin and the southern Gulf of Guayaquil. Classic biomarker, extended diamondoid, and isotope studies indicated that almost all oils from the Progreso Basin Province underwent biodegradation and were generated from multiple Tertiary source rocks deposited in a marine setting with significant influx of terrestrial organic material. Three families of oils were identified. Oil-source rock correlations suggest that the Socorro, Dos Bocas and San Eduardo formations can be considered as contributors to the studied oils. Geochemical data and previous thermal models point towards two probable hydrocarbon kitchens defined in the deepest parts of the basin as well as a third possible kitchen extended offshore beyond the Santa Elena Peninsula. Highlights: Three oil types were identified in the Santa Elena Peninsula and Gulf of Guayaquil. Different levels of alteration are noted in the oils from the Santa Elena Peninsula. Most oils from the onshore fields are the result of the mixing of two oil charges. Three source rocks of Tertiary age are proposed in the Progreso Basin Province. The Socorro Formation is the main source rock for most oils from the onshore fields.