Alkali metal ion binding using cyclic polyketones. Issue 18 (16th February 2022)
- Record Type:
- Journal Article
- Title:
- Alkali metal ion binding using cyclic polyketones. Issue 18 (16th February 2022)
- Main Title:
- Alkali metal ion binding using cyclic polyketones
- Authors:
- Ozawa, Narito
Shivakumar, Kilingaru I.
Murugavel, Muthuchamy
Inaba, Yuya
Yoneda, Tomoki
Ide, Yuki
Pirillo, Jenny
Hijikata, Yuh
Inokuma, Yasuhide - Abstract:
- Abstract : Cyclic polyketones composed of acetylacetone analogues showed crown ether-like alkali metal ion binding in less polar solvents. Their cation-binding properties were used for the Finkelstein reaction and the design of new cation-binding hosts. Abstract : Cyclic oligoketones composed of 3, 3-dimethylpentane-2, 4-diones showed crown ether-like alkali metal ion binding behavior with association constants up to 1.7 × 10 4 M −1 in chloroform/acetonitrile (v/v, 9/1). The binding properties have been used for catalysis in the Finkelstein reaction in a low-polarity solvent. Furthermore, novel ion-binding hosts were generated by terminal functionalization of linear polyketones.
- Is Part Of:
- Chemical communications. Volume 58:Issue 18(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 18(2022)
- Issue Display:
- Volume 58, Issue 18 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 18
- Issue Sort Value:
- 2022-0058-0018-0000
- Page Start:
- 2971
- Page End:
- 2974
- Publication Date:
- 2022-02-16
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc00361a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 21061.xml