Photocatalytic activity enhancement of Cu2O cubes functionalized with 2-ethynyl-6-methoxynaphthalene through band structure modulation. Issue 10 (22nd February 2022)

• Record Type: Journal Article
• Authors: Patra, Anindya Sundar; Kao, Jui-Cheng; Chan, Shang-Ju; Chou, Po-Jung; Chou, Jyh-Pin; Lo, Yu-Chieh; Huang, Michael H.
• Is Part Of: Journal of materials chemistry. Volume 10:Issue 10(2022)
• Page Start: 3980
• Page End: 3989
• Publication Date: 2022-02-22
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d1tc05278k
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Inert Cu2 O cubes become photocatalytically active with 2E-6-MN functionalization. The molecule-derived bands within the band gap of Cu2 O and charge density distribution over the molecule contribute to the photocatalytic activity appearance. Abstract : Since the exciting discovery that binding of 4-ethynylaniline on inert Cu2 O cubes makes the functionalized cubes highly photocatalytically active toward methyl orange (MO) degradation, binding of 2-ethynyl-6-methoxynaphthalene (2E-6MN) molecules was found to produce a similar effect to activate Cu2 O cubes. A moderate activity enhancement was observed for the functionalized Cu2 O rhombic dodecahedra, while the activity of octahedra only improves slightly. Thus, the degree of photocatalytic activity enhancement is highly facet-dependent. Electron, hole, and radical scavenger tests confirm the photocatalysis results. Electrochemical impedance measurements also show a reduced charge transfer resistance after 2E-6MN modification for cubes and rhombic dodecahedra. Moreover, density functional theory (DFT) calculations have revealed the emergence of narrow bands within the band gaps of Cu2 O{100} and {110} surfaces, but not on the {111} surface. Charge density distribution analysis is also insightful to understand the pronounced photocatalytic activity of the modified Cu2 O cubes. Surface functionalization with conjugated molecules represents a new strategy to activate or enhance photoinduced charge transfer of semiconductor materials.