Cellulose electrospinning from ionic liquids: The effects of ionic liquid removal on the fiber morphology. (1st June 2022)

• Record Type: Journal Article
• Authors: Krugly, Edvinas; Pauliukaityte, Ingrida; Ciuzas, Darius; Bulota, Mindaugas; Peciulyte, Laura; Martuzevicius, Dainius
• Is Part Of: Carbohydrate polymers. Volume 285(2022)
• Publication Date: 2022-06-01
• Subjects: Regenerated cellulose fibers -- Wet-type electrospinning -- Ionic liquids -- Elution; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2022.119260
• Languages: English
• ISSNs: 0144-8617

Abstract

Abstract: The importance of the cellulose cycle has been increasing during the last decade along the ambitious targets of bioeconomy, however many novel fabrication processes yet lack of technological robustness. We present the optimization process for the fabrication of cellulose fibrous matrix by wet electrospinning via the controlled removal of the ionic liquids in order to avoid the formation of film-like structures. Fibers were produced on a bespoke wet-type electrospinning rig from cotton cellulose solutions of 3% in different types of ionic liquids (BMIMAc/C10MIMCl/EMIMAc). Three stage elution with a range of elution ratios using deionized water were applied to coagulate cellulose and remove residuals of ionic liquid. A variety of fibrous morphologies has been obtained. In case of a high water/IL ratio, the median fiber width across all ionic liquids was 0.4 μm, with the porosity at 92.3% and the pore diameter at 155 μm. The increasing elution ratio positively affected separate cellulose fiber formation, crystallinity, and mechanical strength of formed structures. Graphical abstract: Unlabelled Image Highlights: The increasing elution ratio positively affected separate cellulose fiber formation Elution ratio positively influenced crystallinity and mechanical strength of formed matrixes BMIMAc appeared as the most difficult to leach from cellulose fiber based on the elution efficiency sequence. The electrospun and postprocessed cellulose was transformed from type I to type II (amorphous).