Direct synthesis of higher alcohols from syngas over modified Mo2C catalysts under mild reaction conditions. Issue 5 (4th February 2022)

• Record Type: Journal Article
• Authors: Wang, Caiqi; Yu, Hailing; Lin, Tiejun; Qi, Xingzhen; Yu, Fei; Zhong, Liangshu; Sun, Yuhan
• Is Part Of: Catalysis science & technology. Volume 12:Issue 5(2022)
• Page Start: 1697
• Page End: 1708
• Publication Date: 2022-02-04
• Subjects: Catalysis -- Periodicals; 541.395
• DOI: 10.1039/d1cy02186a
• Languages: English
• ISSNs: 2044-4753

Abstract

Abstract : The RhK/Mo2 C catalyst exhibited remarkable selectivity for higher alcohols synthesis from syngas under mild reaction conditions owing to the interface sites between Rh and Mo2 C promoted by K, which greatly facilitated CO insertion. Abstract : Direct syngas conversion to higher alcohols with high selectivity under mild reaction conditions has attracted much attention but still remains a great challenge. Herein, we reported that the addition of Rh and K promoters to Mo2 C (RhK/Mo2 C) can significantly increase alcohols selectivity to 44.4% under a mild reaction pressure of 1 MPa. Mechanism study illustrated that interface sites between Rh and Mo2 C promoted by K effectively contributed to the improved catalytic performance. The K promoter not only promoted the dispersion of Rh with a partial Rh δ + state under working conditions but also suppressed further hydrogenation of olefins. In addition, the highly dispersed Rh δ + species increased the concentration of non-dissociated CO* intermediates and greatly improved the coupling ability of CO and alkyl species to form alcohols. This work provides a promising strategy to design efficient heterogeneous catalysts at low pressure for higher alcohols synthesis over Mo2 C-based catalysts.