Diol responsive viscosity increase in a cetyltrimethylammonium bromide/sodium salicylate/3-fluorophenylboronic acid micelle system. Issue 11 (25th February 2022)

• Record Type: Journal Article
• Authors: Miki, Ryotaro; Yamaki, Tsutomu; Uchida, Masaki; Natsume, Hideshi
• Is Part Of: RSC advances. Volume 12:Issue 11(2022)
• Page Start: 6668
• Page End: 6675
• Publication Date: 2022-02-25
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d1ra08831a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : We report a novel smart micellar system utilising a phenylboronic acid (PBA) derivative whose viscosity increases on adding diol compounds such as sugar or sugar alcohol. Abstract : We report a novel smart micellar system utilising a phenylboronic acid (PBA) derivative whose viscosity increases on adding diol compounds such as sugar or sugar alcohol. We prepared a typical worm-like micelle (WLM) system in 100 mM cetyltrimethylammonium bromide (CTAB)/70 mM sodium salicylate (NaSal), which showed high zero-shear viscosity ( η 0 ). Upon the addition of 20 mM 3-fluorophenylboronic acid (3FPBA) to the WLM system, η 0 decreased by 1/300 that of the system without 3FPBA. Furthermore, upon the addition of 1.12 M fructose (Fru) and 1.12 M sorbitol (Sor) to the CTAB/NaSal/3FPBA system, η 0 increased by 50-fold and 30-fold, respectively. 19 F NMR spectral results of the systems using 4-fluorosalicylic acid (FSal) instead of NaSal demonstrated that the FSal/3FPBA-complex interacts with CTAB. Moreover, the addition of sugar or sugar alcohol to the micellar system leads to a decrease in the amount of FSal/3FPBA-complex interacting with CTA + and an increase in the amount of 3FPBA/Fru or Sor-complex, which does not interact with CTA + . These changes in molecular interactions induce the elongation of the WLMs and increase the viscosity of the system. This system utilises the competitive cyclic ester bond between the NaSal/3FPBA and 3FPBA/sugar or sugar alcohol to induce viscosity changes.