Electromagnetic wave absorption superalloy/graphite magnetic nanocapsules applied in wide temperature range. (1st April 2022)

• Record Type: Journal Article
• Authors: Lei, Z.X.; Li, S.Z.; Zhang, A.Q.; Song, Y.H.; He, N.; Li, M.Z.; Geng, D.Y.; Liu, W.; Ma, S.; Zhang, Z.D.
• Is Part Of: Composites. Number 234(2022)
• Publication Date: 2022-04-01
• Subjects: Metal-matrix composites (MMCs) -- Nano-structures -- Magnetic properties -- High-temperature properties; Composite materials -- Periodicals; Materials science -- Periodicals; Composite materials; Periodicals; Electronic journals; 620.118
• DOI: 10.1016/j.compositesb.2022.109692
• Languages: English
• ISSNs: 1359-8368

Abstract

Abstract: The magnetic nanocapsules composed of soft-magnetic core and dielectric graphite shell in nanoscale are of great significance for electromagnetic wave (EMW) absorbing materials. As an ideal model system, novel nanocomposite superalloy/graphite FeNi3 @C nanocapsules were synthesized that showed two significant advantages including extremely stable magnetic behavior from 5 K to 300 K and strong anti-oxidation ability up to 719 K, simultaneously. The tuning regularity of enhanced EMW absorption, including magnetic core, filling ratio, dielectric shell, was systemically investigated. A reflection loss (RL) - 47.26 dB at 13 GHz and an absorption bandwidth 7.04 GHz (RL < −10 dB) with absorber thicknesses 3 mm were obtained while the effective absorbing bandwidth remained at top level in magnetic nanocapsules system. This work not only extends EMW absorption application of magnetic nanocapsules in wide temperature range, but also provides a clear optimal sequence to support the material design strategy to achieve best EMW absorption in nanocomposite systems. Highlights: The superalloy/graphite (FeNi3 @C) nanocapsules were synthesized and exhibited effective absorbing bandwidth 7.04 GHz. The FeNi3 @C nanocapsules exhibit stable magnetic stability from 5 K to 300 K. The strong resistance to high temperature oxidation until to 719 K was found in FeNi3 @C nanocapsules. Based on above two advantages, FeNi3 @C nanocapsules can be applied in wide temperature range EMW absorption. The optimal tuning regularity of enhanced EMW absorption was found with FeNi3 @C nanocapsules as the model system.