The fabrication and characterization of half-Heusler YPdBi thin films. (February 2022)

• Record Type: Journal Article
• Authors: Polat, Ozgur; Arregi, Jon Ander; Horák, Michal; Polčák, Josef; Bukvišová, Kristýna; Zlámal, Jakub; Šikola, Tomáš
• Is Part Of: Journal of physics and chemistry of solids. Volume 161(2022)
• Publication Date: 2022-02
• Subjects: Half-Heusler compounds -- Thin films -- Magnetron sputtering -- STEM -- Electrical properties; Solids -- Periodicals; Solides -- Périodiques; Solids; Periodicals; 530.41
• DOI: 10.1016/j.jpcs.2021.110447
• Languages: English
• ISSNs: 0022-3697

Abstract

Abstract: The electrical, optical, and magnetic properties of half-Heusler compounds make them novel interesting materials being studied by many groups worldwide. The synthesis of YPdBi, a member of half-Heusler compounds, thin films have been achieved at different deposition temperatures such as 360 °C and 470 °C by employing magnetron co-sputtering technique. X-ray diffraction (XRD) examinations have revealed that the film deposited at 360 °C has a slightly larger lattice parameter, 6.82 Å, than the film fabricated at 470 °C, having 6.73 Å. The induced strain of the films has been 2.1% and 0.7% for the films deposited at 360 °C and 470 °C, respectively. X-ray photoelectron spectroscopy (XPS) investigations have revealed the obtained films have the stoichiometry close to the 1:1:1 ratio. Scanning electron microscopy (SEM) studies have shown that surface topography varies dramatically as the deposition temperature advances. Furthermore, high-resolution scanning transmission electron microscopy (STEM) has shown that layer-plus-island growth known as the Stranski–Krastanov (SK) growth mode, taking place due to minimization of strain energy, leads to the island formation from a specific film thickness on. It has been shown that while the resistance of the sample grown at 470 °C changes abruptly at 2.45 K, which indicates the onset of superconductivity, the sample deposited at 360 °C does not show this effect. The absence of the onset of superconductivity in this latter case might be associated with the lattice strain and intensive scattering in this sample. Highlights: Half-Heusler YPdBi thin films were synthesized by co-magnetron sputtering technique. The magnetotransport properties of half-Heusler YPdBi thin films have been investigated. The sample deposited at 470 °C indicates the onset of superconductivity at 2.45 K.