Roles of CO2 and H2O in premixed turbulent oxy-fuel combustion. (15th December 2018)

• Record Type: Journal Article
• Authors: Zhong, Shenghui; Zhang, Fan; Peng, Zhijun; Bai, Fuqiang; Du, Qing
• Is Part Of: Fuel. Volume 234(2018)
• Page Start: 1044
• Page End: 1054
• Publication Date: 2018-12-15
• Subjects: 1-D One-Dimensional -- 2-D Two-Dimensional -- CCS Carbon Capture and Storage -- DNS Direct Numerical Simulation -- HRR Heat Release Rate -- PDF Probability Density Function -- PISO Pressure Implicit Split Operator -- PRR Pressure Rising Rate -- ROP Rate of Production; Oxy-fuel combustion -- Direct numerical simulation -- CO2 effect -- H2O effects; Fuel -- Periodicals; Coal -- Periodicals; Coal; Fuel; Periodicals; 662.6
• DOI: 10.1016/j.fuel.2018.07.135
• Languages: English
• ISSNs: 0016-2361

Abstract

Highlights: A low Mach DNS reacting flow solver is developed in OpenFOAM. The chemical effect of H2 O and CO2 is analyzed by chemical reaction path ways. Cool down effect of CO2 and H2 O under high temperature and pressure are investigated. The response of flame surface to curvature effects are diverse with different dilute agent. Suitable H2 additives to CH4 could counteract the passive effect of CO2 on flame speed. Abstract: A series of Two-Dimensional Direct Numerical Simulation (2-D DNS) cases are performed to investigate the effects of CO2 and H2 O on premixed turbulent oxy-fuel combustion (case oxy-H2 O, case oxy-CO2 ) in a constant vessel. A DNS solver for low Mach reacting flow is developed based on open source code OpenFOAM. The chemical effects of CO2 and H2 O are isolated by a pair of artificial species. 2-D DNS results shows the flame surface of oxy-CO2 case trends to be wrinkled with small convex and concave structures due to a lower laminar flame speed and a smaller effective Lewis number. Moreover, the response of flame surface to the curvature is different with corresponding dilute agent. Owing to the high binary diffusion coefficient between H2 O and H, the negative curvature effect on fast diffusing species, e.g. H and H2, are enhanced in oxy-H2 O, and results in a higher burning velocity. The effects of CO2 on H transport are contrary to the effects of H2 O and the oxidation process is slowed due to the elementary reaction CO2 + H ⇔ CO + OH, which result in a more uniform Heat Release Rate (HRR) distribution on flame surface. In addition, chemical reaction pathway analysis is performed to elucidate the chemical effects of CO2 and H2 O. It is found that CO2 and H2 O will cool down the temperature of burnt region compared with N2 . Finally, an alternative solution is raised to counteract the negative effect of CO2 on flame speed, which should be useful in the development and design of oxy-fuel combustion.