Self-assembled CoS2 nanoparticles wrapped by CoS2-quantum-dots-anchored graphene nanosheets as superior-capability anode for lithium-ion batteries. (10th November 2015)

• Record Type: Journal Article
• Authors: He, Jiarui; Chen, Yuanfu; Li, Pingjian; Fu, Fei; Wang, Zegao; Zhang, Wanli
• Is Part Of: Electrochimica acta. Volume 182(2015)
• Page Start: 424
• Page End: 429
• Publication Date: 2015-11-10
• Subjects: Graphene -- Cobalt sulfides -- Quantum dots -- Wrapped -- Lithium-ion battery; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2015.09.131
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: For the first time, self-assembled CoS2 nanoparticles wrapped by CoS2 -quantum-dots anchored graphene nanosheets (CoS2 NP@G-CoS2 QD) are synthesized by a facile l -cysteine-assisted hydrothermal reaction. When the composite is used as anode in lithium-ion batteries (LIBs), it shows superior electrochemical performance: the reversible specific capacity is as large as 1048 mAh g −1 ; the 300 th -cycle capacity still maintains 831 mAh g −1 even at 1 A g −1 ; the rate capacity remains 411 mAh g −1 even at 10 A g −1, which is the highest value ever reported at such high current density for CoS2 based materials. The excellent electrochemical performance is attributed to the unique structure with CoS2 nanoparticles homogeneously wrapped by highly flexible and conductive few-layer graphene nanosheets adhering abundant CoS2 quantum dots, which can effectively suppress the aggregation of CoS2 nanoparticles, accommodate the volume change during the cycle processes and maintain high electrical conductivity of the electrode. The CoS2 NP@G-CoS2 QD composite is promising for superior-capability anode for LIBs and can be further extended to broad applications in supercapacitors, sensors, and catalysis.