Constraining Emissions of Volatile Organic Compounds Over the Indian Subcontinent Using Space‐Based Formaldehyde Measurements. Issue 19 (15th October 2019)

• Record Type: Journal Article
• Authors: Chaliyakunnel, Sreelekha; Millet, Dylan B.; Chen, Xin
• Is Part Of: Journal of geophysical research. Volume 124:Issue 19(2019)
• Page Start: 10525
• Page End: 10545
• Publication Date: 2019-10-15
• Subjects: Atmospheric physics -- Periodicals; Geophysics -- Periodicals; 551.5
• DOI: 10.1029/2019JD031262
• Languages: English
• ISSNs: 2169-897X

Abstract

Abstract: India is an air pollution mortality hot spot, but regional emissions are poorly understood. We present a high‐resolution nested chemical transport model (GEOS‐Chem) simulation for the Indian subcontinent and use it to interpret formaldehyde (HCHO) observations from two satellite sensors (OMI and GOME‐2A) in terms of constraints on regional volatile organic compound (VOC) emissions. We find modeled biogenic VOC emissions to be overestimated by ~30–60% for most locations and seasons, and derive a best estimate biogenic flux of 16 Tg C/year subcontinent‐wide for year 2009. Terrestrial vegetation provides approximately half the total VOC flux in our base‐case inversions (full uncertainty range: 44–65%). This differs from prior understanding, in which biogenic emissions represent >70% of the total. Our derived anthropogenic VOC emissions increase slightly (13–16% in the base case, for a subcontinent total of 15 Tg C/year in 2009) over RETRO year 2000 values, with some larger regional discrepancies. The optimized anthropogenic emissions agree well with the more recent CEDS inventory, both subcontinent‐wide (within 2%) and regionally. An exception is the Indo‐Gangetic Plain, where we find an underestimate for both RETRO and CEDS. Anthropogenic emissions thus constitute 37–50% of the annual regional VOC source in our base‐case inversions and exceed biogenic emissions over the Indo‐Gangetic Plain, West India, and South India, and over the entire subcontinent during winter and post‐monsoon. Fires are a minor fraction (<7%) of the total regional VOC source in the prior and optimized model. However, evidence suggests that VOC emissions in the fire inventory used here (GFEDv4) are too low over the Indian subcontinent. Key Points: Natural emissions from terrestrial plants provide approximately half the total source of atmospheric volatile organic compounds over the Indian subcontinent Anthropogenic sources are 37–50% of volatile organic compound emissions over the subcontinent and are slightly underestimated in the prior Fires emissions are underestimated in the prior model but are still only a minor fraction of the regional volatile organic compound source