Synthesis, Stability and Reactivity of α‐Fluorinated Azidoalkanes. Issue 4 (6th November 2019)

• Record Type: Journal Article
• Authors: Bakhanovich, Olga; Beier, Petr
• Is Part Of: Chemistry. Volume 26:Issue 4(2020)
• Page Start: 773
• Page End: 782
• Publication Date: 2019-11-06
• Subjects: azides -- fluorine -- synthetic methods -- triazole; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201903627
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Organic α‐fluorinated azidoalkanes appeared in the literature for the first time half a century ago. However, for a long time they remained undeveloped and were regarded as chemical curiosities. Recent advances in the preparation of α‐fluorinated azidoalkanes as well as studies on their stability and reactivity opened up their broader synthetic potential for the preparation of valuable fluorinated and non‐fluorinated compounds. Abstract : Synthetic approaches to fluorinated azides (with emphasis on α, α‐difluorinated azidoalkanes), their properties, stability and transformations are reviewed.