Interface nanoengineering of a core-shell structured biobased fire retardant for fire-retarding polylactide with enhanced toughness and UV protection. (15th February 2022)

• Record Type: Journal Article
• Authors: Yu, Yueming; Zhang, Yan; Xi, Liangdong; Zhao, Zhinuo; Huo, Siqi; Huang, Guobo; Fang, Zhengping; Song, Pingan
• Is Part Of: Journal of cleaner production. Volume 336(2022)
• Publication Date: 2022-02-15
• Subjects: Dispersion -- Graphene oxide -- Flame retardancy -- Toughness -- Polylactide; Factory and trade waste -- Management -- Periodicals; Manufactures -- Environmental aspects -- Periodicals; Déchets industriels -- Gestion -- Périodiques; Usines -- Aspect de l'environnement -- Périodiques; 628.5
• DOI: 10.1016/j.jclepro.2022.130372
• Languages: English
• ISSNs: 0959-6526

Abstract

Abstract: In this work, we found a very effective method to adjust the polarity of the fillers to promote its good dispersion in matrix by using an organic-solvent-free assembling strategy. With the coating of polyethylenimine-decorated graphene oxide (GO-PEI), the as-prepared biobased core-shell graphene oxide hybrid (BCSGOH) can distribute more homogeneously in the polylactide (PLA) matrix, compared with the bio-derived core-shell flame retardant (CSFR) with higher polarity. The polarity analysis of BCSGOH, CSFR and PLA indicated that the polarity of BCSGOH had a better match with that of PLA, and the interfacial tension (0.8 mN/m) between BCSGOH and PLA was much lower than that (12.0 mN/m) between CSFR and PLA. Consequently, the better flame retardancy, impact toughness and UV-shielding properties of PLA/BCSGOH composites were achieved. 6 wt% of BCSGOH endowed PLA with the best comprehensive properties, such as the UL94 V-0 rating, the limiting oxygen index (LOI) of 30.0%, and notched impact strength of 12.38 kJ/m 2 . Hence, this work offers a conducive, facile and green strategy to create high-performance fire-safe bioplastics. Graphical abstract: Image 1 Highlights: A surface-nanoengineered biobased core-shell structured fire retardant, BCSGOH, is prepared. BCSGOH is uniformly dispersed in the PLA matrix because of a low interfacial tension. 6 wt% BCSGOH enables PLA to achieve a desirable UL-94 V-0 rating. The addition of BCSGOH leads to a 59% increase in the impact toughness of PLA. The resultant fire-retardant PLA exhibits an improved UV-resistance.