A review on sensing and catalytic activity of nano-catalyst for synthesis of one-step ammonia and urea: Challenges and perspectives. (March 2022)

• Record Type: Journal Article
• Authors: Qureshi, Saima; Mumtaz, Mudassar; Chong, Fai Kait; Mukhtar, Ahmad; Saqib, Sidra; Ullah, Sami; Mubashir, Muhammad; Khoo, Kuan Shiong; Show, Pau Loke
• Is Part Of: Chemosphere. Volume 291:Part 3(2022)
• Publication Date: 2022-03
• Subjects: Catalyst -- Magnetic chemical reaction -- Adsorption -- One-step green synthesis; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2021.132806
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: One of the most significant chemical operations in the past century was the Haber-Bosch catalytic synthesis of ammonia, a fertilizer vital to human life. Many catalysts are developed for effective route of ammonia synthesis. The major challenges are to reduce temperature and pressure of process and to improve conversion of reactants produce green ammonia. The present review, briefly discusses the evolution of ammonia synthesis and current advances in nanocatalyst development. There are promising new ammonia synthesis catalysts of different morphology as well as magnetic nanoparticles and nanowires that could replace conventional Fused-Fe and Promoted-Ru catalysts in existing ammonia synthesis plants. These magnetic nanocatalyst could be basis for the production of magnetically induced one-step green ammonia and urea synthesis processes in future. Graphical abstract: Image 1 Highlights: Reduced temperature and pressure, a challenge towards ammonia synthesis process. One step urea synthesis process from ammonia at ambient conditions. Magnetically induced chemical reaction, an alternative route for synthesis of ammonia and urea. Kinetic analysis of ammonia and urea have been reviewed critically. Perspectives on catalytic activity of nano-catalyst are discussed for the production of green ammonia.