High‐Precision Size Recognition and Separation in Synthetic 1D Nanochannels. (20th September 2019)

• Record Type: Journal Article
• Authors: Wang, Ping; Chen, Xinyi; Jiang, Qiuhong; Addicoat, Matthew; Huang, Ning; Dalapati, Sasanka; Heine, Thomas; Huo, Fengwei; Jiang, Donglin
• Is Part Of: Angewandte Chemie. Volume 131:Number 44(2019)
• Page Start: 16069
• Page End: 16074
• Publication Date: 2019-09-20
• Subjects: Kovalente organische Gerüste -- Molekulare Erkennung -- Nanokanäle -- Nanostrukturen -- Trennung; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201909851
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Covalent organic frameworks (COFs) allow elaborate manufacture of ordered one‐dimensional channels in the crystal. We defined a superlattice of COFs by engineering channels with a persistent triangular shape and discrete pore size. We observed a size‐recognition regime that is different from the characteristic adsorption of COFs, whereby pore windows and walls were cooperative so that triangular apertures sorted molecules of one‐atom difference and notch nanogrooves confined them into single‐file molecular chains. The recognition and confinement were accurately described by sensitive spectroscopy and femtosecond dynamic simulations. The resulting COFs enabled instantaneous separation of mixtures at ambient temperature and pressure. This study offers an approach to merge precise recognition, selective transport, and instant separation in synthetic 1D channels. Abstract : Der richtige Kanal : Offene 1D‐Kanäle, deren Poren in dreieckiger Form und einer diskreten Größe in kovalenten organischen Gerüsten gestaltet wurden, konnten molekulare Größenunterschiede erkennen. Dieser Befund eröffnet die Möglichkeit, 1D‐Kanäle für den selektiven Transport und die sofortige molekulare Trennung mit unendlicher Selektivität zu nutzen (siehe Bild).