Mechanistic Insight into Polypyrrole Coating on V2O5 Cathode for Aqueous Zinc‐Ion Battery. Issue 2 (22nd January 2022)

• Record Type: Journal Article
• Authors: Dong, Ruichen; Zhang, Tian; Liu, Jiyuan; Li, Huan; Hu, Deji; Liu, Xingjiang; Xu, Qiang
• Is Part Of: ChemElectroChem. Volume 9:Issue 2(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-01-22
• Subjects: Coating -- Mechanism -- Polypyrrole -- Vanadium oxide -- Zinc-ion battery; Electrochemistry -- Periodicals; 541.37
• DOI: 10.1002/celc.202101441
• Languages: English
• ISSNs: 2196-0216

Abstract

Abstract: The aqueous zinc‐ion batteries have been extensively studied among energy storage devices due to the excellent electrochemical performance, high safety, and low cost. Recently, vanadium oxide (V2 O5 ) cathode materials have received much attention owing to the high theoretical capacity. However, it is still hindered by some drawbacks, including poor electronic conductivity, sluggish kinetics for zinc‐ion diffusion, and cathode dissolution in the electrolyte. To address these issues, the cathode material of V2 O5 particles coated by a layer of polypyrrole (V2 O5 /PPy) has been prepared by an environmental favorable route in this work. It was found that the PPy coating layer can efficiently enhance the cyclic and rate performance. The obtained V2 O5 @PPy cathode demonstrates a high capacity retention of 95.6 % after 300 cycles, and deliver a high‐rate capacity of 68.4 mAh g −1 at 5 A g −1 . The theoretical computation clarifies that PPy coating can weaken the electrostatic interaction between V2 O5 matrix and zinc‐ion and therefore boost the insertion/extraction process of Zn 2+ ion. This work provides a valuable insight into the underlying action mechanism of polymer‐coated cathode materials for Zn 2+ storage in aqueous zinc‐ion batteries. Abstract : Facilitating zinc‐ion storage : To explore the action mechanism of PPy coating on the V2 O5 cathode for aqueous zinc‐ion batteries, this work gives mechanistic insight into the action mechanism of PPy coating on the performance of V2 O5 cathode. Combined experimental results with theoretical computations, it is found that PPy coating boosts the Zn 2+ insertion/extraction by changing the local electric field around V2 O5 particles, facilitating the zinc‐ion storage.