Construction of a Porous Metal–Organic Framework with a High Density of Open Cr Sites for Record N2/O2 Separation (Adv. Mater. 37/2021). Issue 37 (14th September 2021)

• Record Type: Journal Article
• Authors: Zhang, Feifei; Shang, Hua; Wang, Li; Wang, Yong; Yang, Jiangfeng; Xia, Yuanhua; Li, Hao; Li, Libo; Li, Jinping
• Is Part Of: Advanced materials. Volume 33:Issue 37(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-09-14
• Subjects: high‐purity O 2 -- Lewis acid sites -- metal–organic frameworks -- N 2/O 2 separation -- open Cr sites; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.202170291
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract : Spatial Structure Reconstruction In article number 2100866, Jiangfeng Yang, Libo Li, and co‐workers, through optimized spatial structure reconstruction, build TYUT‐96Cr, composed of three kinds of small pore cages using Cr and trimesic acid. Benefitting from the high‐density open Cr sites in the structure, this material features record N2 adsorption volume capacity and N2 /O2 separation selectivity, and is practically useful for upmarket industrial applications.