CsPbI3 Nanocrystals Go with the Flow: From Formation Mechanism to Continuous Nanomanufacturing. (21st November 2021)

• Record Type: Journal Article
• Authors: Antami, Kameel; Bateni, Fazel; Ramezani, Mahdi; Hauke, Cory E.; Castellano, Felix N.; Abolhasani, Milad
• Is Part Of: Advanced functional materials. Volume 32:Number 6(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-11-21
• Subjects: CsPbI 3 nanocrystals -- lead halide perovskites -- microfluidics -- nanomanufacturing -- quantum dots; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.202108687
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Despite the groundbreaking advancements in the synthesis of inorganic lead halide perovskite (LHP) nanocrystals (NCs), stimulated from their intriguing size‐, composition‐, and morphology‐dependent optical and optoelectronic properties, their formation mechanism through the hot‐injection (HI) synthetic route is not well‐understood. In this work, for the first time, in‐flow HI synthesis of cesium lead iodide (CsPbI3 ) NCs is introduced and a comprehensive understanding of the interdependent competing reaction parameters controlling the NC morphology (nanocube vs nanoplatelet) and properties is provided. Utilizing the developed flow synthesis strategy, a change in the CsPbI3 NC formation mechanism at temperatures higher than 150 °C, resulting in different CsPbI3 morphologies is revealed. Through comparison of the flow‐ versus flask‐based synthesis, deficiencies of batch reactors in reproducible and scalable synthesis of CsPbI3 NCs with fast formation kinetics are demonstrated. The developed modular flow chemistry route provides a new frontier for high‐temperature studies of solution‐processed LHP NCs and enables their consistent and reliable continuous nanomanufacturing for next‐generation energy technologies. Abstract : This work presents a facile and scalable high‐temperature nanomanufacturing of cesium lead iodide (CsPbI3 ) nanocrystals (NCs) using a modular flow reactor. The flow chemistry platform integrated with multimodal in situ spectroscopy reveals a detailed understanding of the formation mechanism of CsPbI3 NCs via the hot‐injection synthetic route.