Stepwise synthesis of Zr-based metal–organic frameworks: incorporating a trinuclear zirconocene-based metallo-pyridine ligand. Issue 3 (23rd December 2021)

• Record Type: Journal Article
• Authors: Zhu, Juan; Liu, Zhao-Yang; Li, Shuang-bao; Huang, He; Jiang, Bao-Xu; Zhang, Yu-Teng
• Is Part Of: CrystEngComm. Volume 24:Issue 3(2022)
• Page Start: 475
• Page End: 478
• Publication Date: 2021-12-23
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/d1ce01418h
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Based on a presynthesized Zr3 precursor, two isostructural 2D heterometallic ZrMOFs have been synthesized by a step synthesis strategy. Abstract : Two isostructural heterometallic ZrMOFs (denoted as ZrMOF-Co and ZrMOF-Ni) were obtained by a stepwise synthesis approach. Single-crystal X-ray structural analyses indicate that the two ZrMOFs are both built from trinuclear zirconocene-based metallo-pyridine building blocks, featuring a 2D infinite chain structure. Furthermore, magnetic studies reveal that ZrMOF-Co shows antiferromagnetic performance, while ZrMOF-Ni features a ferromagnetic behavior.