Quasi-isotropic SMMs: slow relaxation of the magnetization in polynuclear CuII/MnII complexes. Issue 5 (25th January 2022)

• Record Type: Journal Article
• Authors: Pilichos, Evangelos; Bhunia, Pradip; Font-Bardia, Mercè; Ghosh, Ashutosh; Mayans, Júlia; Escuer, Albert
• Is Part Of: Dalton transactions. Volume 51:Issue 5(2022)
• Page Start: 1779
• Page End: 1783
• Publication Date: 2022-01-25
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt04074j
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Induced SMM responses for polynuclear systems derived from isotropic cations have been characterized for three Cu II /Mn II clusters with several nuclearities and S ground states. Comparison with isotropic SIMs suggests a similar relaxation mechanism. Abstract : Three field induced SMMs built from quasi-isotropic cations like Cu II and Mn II have been characterized, showing that relatively large clusters with quasi-negligible D and different ground spin states, S = 3/2, 2 or 4, can also exhibit field-induced slow relaxation of magnetization.